The catalytic oxidation of potato starch by [MnIV2 (μ-O)3(tmtacn)2][H2O](CH3COO)2 (Mncat, with tmtacn =1,4,7-trimethyl-1,4,7-triazacyclononane) with H2O2, was recently introduced as a promising alternative to ubiquitous sodium hypochlorite (NaOCl). Here, we report an in-depth investigation into interactions …

The catalytic conversion of oleic acid to aromatics (benzene, toluene, and xylenes, BTX) over a granular H-ZSM-5/Al2O3 catalyst (ϕ 1.2–1.8 mm, 10 g loading) was investigated in a continuous bench-scale fixed-bed reactor (10 g oleic acid h–1). A peak carbon yield of aromatics of 27.4% was obtained at …

The catalytic conversion of glycerol to aromatics (GTA, e.g., benzene, toluene, and xylenes, BTX) over a shaped H-ZSM-5/Al2O3 (60/40 wt%) catalyst was investigated in a continuous fixed-bed reactor to study the addition of the Al2O3 binder in the catalyst formulation on catalyst performance. The experiments …

Herein, Zeolitic imidazolate framework-8 (ZIF-8) is considered as an easy and cheap to prepare alternative catalyst for the isomerization of glucose and production of 5-hydroxymethyl furfural (HMF). For the synthesis of the ZIF-8 catalysts two preparation methods were evaluated, being room temperature …

This report discusses the easy and cheap preparation of SnCl2 exchanged Brønsted acidic Amberlyst-15 ion exchange resin prepared by ion exchange of an aqueous SnCl2 solution at room temperature. The prepared materials were tested in the conversion of sugars, being glucose, fructose and saccharose to …

Materials with semiconducting properties are present in every microelectronic device and form the backbone of our information society. Commonly used inorganic semiconductors are poorly modular and their production is expensive and energetically demanding. Moreover, the use of metals and critical raw …

Het onderzoek beschreven in deze scriptie richt zich op de asymmetrische hydrogenering van cyclohexadienen tot chirale cyclohexanen. Via een regioselectieve kobalt gekatalyseerde Diels-Alder reactie zijn 1,3-gesubstitueerde cyclohexenen gesynthetiseerd. Deze cyclohexenen dienen als substraten voor de …

A high resolution infrared spectrum of species formed in a nitrogen-hydrogen plasma expansion was recorded. A cavity ring down detection scheme was used to record a rotationally resolved spectrum in the region from 3300 cm-1 to 3380 cm-1. Using the relative intensities and line positions it was determined …

The scope of this thesis of Gerrit Bouwhuis, lecturer at Saxion Research Centre for Design and Technology in Enschede is the development of a new industrial applicable pre-treatment process for cotton based on catalysis. The pre-treatment generally consists of desizing, scouring and bleaching. These …

Michael additions of α-nitroesters with enones and α,β-unsaturated aldehydes result in quantitative conversions to the corresponding 1,4-adducts by performing the reactions in water in the presence of ytterbium triflate as water-tolerant Lewis acid.